All perfect praise be to Allaah, The Lord of the Worlds. I testify that there is none worthy of worship except Allaah and that Muhammad is His slave and Messenger.
The wife is not obliged to spend on herself or on her husband or his sister and others, and she does not have to pay the household expenses such as water or electricity bills and the like, unless she does that by her own proper will as a voluntary act.
Indeed, it is the husband who is responsible for spending on himself and his wife, and then if he wishes to voluntarily spend on his rich sister, he may do so. However, he is not entitled to be negligent in spending on his family in order to spend on his sister and others, and he should not compel his wife to do so.
In any case, this issue should be discussed in a wise and gentle manner with him in order to convince his sister to bear the costs of water and electricity consumption, unless her brother or anyone else volunteers to pay those costs for her.
It should be mentioned as well that your donation is praised because being generous to the husband and helping him and being kind to his family and his relatives are all part of having a good marital relationship, and represent a good act of kindness that is praised, and its consequences will be goodness, Allaah willing.
With regard to spending, the spouses should deal with each other with tolerance so that their marriage would be stable and far from disputes and dissension.
Allaah Knows best.